Synthesis, characterization, and polymerization of new methacrylate esters having pendant amide moieties
Journal of Macromolecular Science - Pure and Applied Chemistry, cilt.39 A, sa.5, ss.405-417, 2002 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 39 A Sayı: 5
- Basım Tarihi: 2002
- Doi Numarası: 10.1081/ma-120003963
- Dergi Adı: Journal of Macromolecular Science - Pure and Applied Chemistry
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.405-417
- Anahtar Kelimeler: α-chloro-N-aryl or -N-alkyl acetamide, Methacrylate esters, Photocrosslinking properties, Thermal decomposition temperature
- Uşak Üniversitesi Adresli: Evet
Özet
In this paper, the synthesis of a number of new methacrylate esters containing amide group are described. The monomers produced from the reaction of corresponding α-chloro-N-aryl or -N-alkyl acetamides with sodium methacrylate were polymerized with AIBN as initiator. The monomers and their polymers were characterized by IR, 1H- and 13C-NMR spectroscopy. The glass transition temperature and thermal decomposition temperature of the polymers were investigated by DSC-50 and TGA-50 thermobalance, respectively. The photocrosslinking properties of the polymers were also discussed.