Synthesis, characterization, and polymerization of new methacrylate esters having pendant amide moieties

Erol I., SOYKAN C.

Journal of Macromolecular Science - Pure and Applied Chemistry, cilt.39 A, sa.5, ss.405-417, 2002 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 39 A Sayı: 5
  • Basım Tarihi: 2002
  • Doi Numarası: 10.1081/ma-120003963
  • Dergi Adı: Journal of Macromolecular Science - Pure and Applied Chemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.405-417
  • Anahtar Kelimeler: α-chloro-N-aryl or -N-alkyl acetamide, Methacrylate esters, Photocrosslinking properties, Thermal decomposition temperature
  • Uşak Üniversitesi Adresli: Evet

Özet

In this paper, the synthesis of a number of new methacrylate esters containing amide group are described. The monomers produced from the reaction of corresponding α-chloro-N-aryl or -N-alkyl acetamides with sodium methacrylate were polymerized with AIBN as initiator. The monomers and their polymers were characterized by IR, 1H- and 13C-NMR spectroscopy. The glass transition temperature and thermal decomposition temperature of the polymers were investigated by DSC-50 and TGA-50 thermobalance, respectively. The photocrosslinking properties of the polymers were also discussed.