Synthesis, characterization, and polymerization of new methacrylate esters having pendant amide moieties

Erol I., SOYKAN C.

Journal of Macromolecular Science - Pure and Applied Chemistry, vol.39 A, no.5, pp.405-417, 2002 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 39 A Issue: 5
  • Publication Date: 2002
  • Doi Number: 10.1081/ma-120003963
  • Journal Name: Journal of Macromolecular Science - Pure and Applied Chemistry
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.405-417
  • Keywords: α-chloro-N-aryl or -N-alkyl acetamide, Methacrylate esters, Photocrosslinking properties, Thermal decomposition temperature
  • Uşak University Affiliated: Yes

Abstract

In this paper, the synthesis of a number of new methacrylate esters containing amide group are described. The monomers produced from the reaction of corresponding α-chloro-N-aryl or -N-alkyl acetamides with sodium methacrylate were polymerized with AIBN as initiator. The monomers and their polymers were characterized by IR, 1H- and 13C-NMR spectroscopy. The glass transition temperature and thermal decomposition temperature of the polymers were investigated by DSC-50 and TGA-50 thermobalance, respectively. The photocrosslinking properties of the polymers were also discussed.