Synthesis of p-methoxyphenacylmethacrylate: Its characterization, polymerization and preparation of the oxime and 2,4-dinitrophenylhydrazone derivatives

SOYKAN, CENGİZ; Özdemir, Eyüp; Ahmedzade, Misir

doi:10.1016/s1381-5148(00)00069-9

Synthesis of p-methoxyphenacylmethacrylate: Its characterization, polymerization and preparation of the oxime and 2,4-dinitrophenylhydrazone derivatives

SOYKAN C., Özdemir E., Ahmedzade M.

Reactive and Functional Polymers, cilt.47, sa.2, ss.87-92, 2001 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 47 Sayı: 2
Basım Tarihi: 2001
Doi Numarası: 10.1016/s1381-5148(00)00069-9
Dergi Adı: Reactive and Functional Polymers
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.87-92
Uşak Üniversitesi Adresli: Evet

Özet

p-Methoxyphenacylmethacrylate (MPMA) was prepared from p-methoxyphenacylbromide and sodium methacrylate. Polymerization of the monomer was carried out in 1,4-dioxane solution in presence of 2,2′-azobisisobutyronitrile as an initiator at 70 °C. The monomer and the polymer microstructure were investigated by FT-IR, 1H-NMR and 13C-NMR techniques. The oxime and hydrazone derivatives of poly(MPMA) were also prepared and characterized by FT-IR, TGA and DSC.