Synthesis of phenacylmethacrylate: Its characterization and polymerization

Özdemir E., SOYKAN C., Cos̈kun M., Ahmedov M. A.

Journal of Macromolecular Science - Pure and Applied Chemistry, cilt.34, sa.3, ss.551-557, 1997 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 34 Sayı: 3
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1080/10601329708014982
  • Dergi Adı: Journal of Macromolecular Science - Pure and Applied Chemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.551-557
  • Anahtar Kelimeler: Phenacylmethacrylate, Poly (Phenacylmethacrylate -Co-Styrene), Poly (phenacylmethacrylate), Solubility parameter, Thermal analysis
  • Uşak Üniversitesi Adresli: Evet

Özet

Phenacyimethacrylate (PAMA), a new monomer containing two carbonyl groups (C=O), was obtained from phenacyl chloride and sodium methacrylate. The homopolymer of PAMA and its copolymer with styrene were prepared in dioxane by using benzoylperoxide (Bz2O2) as initiator. IR, 1H-NMR and 13C-NMR techniques were used to identify the structure of the monomer and polymers. The density of monomer, homopolymer and copolymer were found to be 1.13; 1.35 and 1.10 gr/ml respectively. Also, limit viscosity numbers, solubility parameters, glass transition and decomposition temperatures of polymers were determined.