Copolymers of phenacyl methacrylate with glycidyl methacrylate: synthesis, characterization and monomer reactivity ratios

SOYKAN C., Ahmedzade M., Coşkun M.

European Polymer Journal, cilt.36, sa.8, ss.1667-1675, 2000 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 36 Sayı: 8
  • Basım Tarihi: 2000
  • Doi Numarası: 10.1016/s0014-3057(99)00230-x
  • Dergi Adı: European Polymer Journal
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1667-1675
  • Uşak Üniversitesi Adresli: Evet

Özet

Copolymers with various proportions of phenacyl methacrylate (PAMA) and glycidyl methacrylate (GMA) were prepared by free radical-polymerization in solution in 1,4-dioxane using 2,2′-azobisisobutyronitrile as initiator at 70°C. The polymers were characterized by infrared and 1H and 13C nuclear magnetic resonance (NMR) spectroscopy. The copolymer compositions were determined by 1H-NMR spectra. The reactivity ratios were calculated by both Fineman-Ross and Kelen-Tudos methods. Glass transition and decomposition temperatures of copolymers were determined.