Reductions of benzene derivatives whose benzylic positions bear oxygen atoms under mild conditions
Helvetica Chimica Acta, cilt.91, sa.12, ss.2299-2307, 2008 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 91 Sayı: 12
- Basım Tarihi: 2008
- Doi Numarası: 10.1002/hlca.200890250
- Dergi Adı: Helvetica Chimica Acta
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.2299-2307
- Uşak Üniversitesi Adresli: Hayır
Özet
Reductions of compounds whose benzylic positions bear O-atoms, such as benzyl alcohol, dibenzyl ether, styrene oxide, benzaldehyde, acetophenone, and benzophenone, to the corresponding non-conjugated dienes were performed by using t-BuOH, Li, and gaseous NH3 in THF at room temperature. In these reductions, it was observed that the functional groups at benzylic positions were reduced first. © 2008 Verlag Helvetica Chimica Acta AG.