Akademik Veri Yönetim Sistemi
Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, cilt.46, sa.9, ss.1426-1431, 2016 (SCI-Expanded)
A novel coordination polymer [(VIVO)2(OH)2(C10H6(COO)2)]∞ based on vanadium(IV) and 2,6-naphthalenedicarboxylato ligand has been prepared by hydrothermal synthetic method. The compound was characterized by elemental analysis, thermogravimetric analysis, Fourier Transform infrared spectroscopy, roomerature magnetic susceptibility measurement, manganometric titration, bond valance sum calculations (BVS), and single-crystal X-ray diffraction method. BVS calculations, manganometric titration, and roomerature magnetic susceptibility measurement showed that the compound has paramagnetic property due to tetravalent vanadium ions. The single-crystal structure analysis of the compound illustrates a 2D metal organic framework structure. Coordination geometry of vanadium ions was a distorted square-pyramid (square-pyramidal coordination environment of oxygen atoms). The compound represents a novel 2D inorganic-organic coordination polymer involving vanadium(IV) and 2,6-naphthalenedicarboxylato ligand.