Synthesis of 1,3-(distal) diamide substituted calix[4]arene based receptors for extraction of chromium (VI)

Durmaz M., BOZKURT S., Sirit A., Yilmaz M.

Supramolecular Chemistry, cilt.19, sa.3, ss.159-165, 2007 (SCI-Expanded, Scopus) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 19 Sayı: 3
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1080/10610270600915979
  • Dergi Adı: Supramolecular Chemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.159-165
  • Anahtar Kelimeler: Calix[4]arene, Diamide, Dichromate anions, Solvent extraction
  • Uşak Üniversitesi Adresli: Evet

Özet

The synthesis of novel diamide derivatives of calix[4]arene by aminolysis of calix[4]arene diesters was reported. The 1H and 13C NMR, data showed that the synthesized compounds exist in the cone conformation. The complexation properties of these calix[4]arenes have been studied towards [image omitted] anions and it has been found that the protonated alkyl ammonium forms of calix[4]arene diamide derivatives (5,11,17,23-tetra-tert-butyl-25,27- (diethylpiperidineacetamido)26,28-dihydroxy-calix[4]arene 3 and 25,27-(diethyl-piperidineacetamido)26,28-dihydroxycalix[4]arene 4) are effective extractants for transferring [image omitted] anions.